Mohr method – determination of chlorides by titration with silver nitrate. The determination of silver or halides by the precipitation of the silver salts is known as argentometric titrations. Here titrant forms precipitate. The dispensed chloride plug is analyzed quantitatively by argentometric titration. If the titration can be performed with high enough precision, the autosampler.

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It is not suitable for titrating against chloride anions because it binds to AgCl more strongly than chloride does. Additional results for the titration curve are shown in Table 9. Waylander 5, 1 10 Methods based on precipitation of silver compounds I are called collectively argentometric methods.

The pH also must be less than 10 to avoid the precipitation of silver hydroxide. Solution during titration should be close to neutral. The Mohr method may be adapted to determine the total chlorine content of a sample by igniting the sample with calciumthen ferric acetate.

Because this equation has two unknowns—g KCl and g NaBr—we need another equation that includes both unknowns. An example of a lab procedure is here 2. Anionic dyes such as dichlorofluorescein are attracted to the particles, and undergo a colour change upon adsorption, representing the end-point. Balancer and stoichiometry calculator. Calcium acetate “fixes” free chlorine, precipitates carbonates, and neutralizes the resultant solution.

In this section we demonstrate a simple method for sketching a precipitation titration curve.

The idea behind is very simple – chlorides are titrated with the silver nitrate solution in the presence of chromate anions. Before precipitation titrimetry became practical, better methods for identifying the end point were necessary. Quantitative chemical analysis 6th ed. As we have done with other argentoetric, we first show how to calculate the titration curve and then demonstrate how we can quickly sketch a reasonable approximation of the titration curve.


They adsorb on the AgCl surface, imparting a negative charge to the particles. Eosin tetrabromofluorescein is suitable for titrating against bromideiodideand thiocyanate anions, giving a sharper end-point than dichlorofluorescein.

Typically, it is used to determine the amount of chloride present in a sample.

9.5: Precipitation Titrations

In the Mohr method, named after Karl Friedrich Mohrpotassium chromate is an indicator, giving red silver chromate after all chloride ions have reacted:. Sign up using Email and Password. Click here to review your answer to this exercise. In low pH silver chromate solubility grows due to the protonation of chromate anions, in high pH silver starts to react with hydroxide anions, precipitating in form of AgOH and Ag 2 O. To calculate the concentration of Cl — we use the K sp expression for AgCl; thus.

Calculate the volume of AgNO aegentometric needed to reach the equivalence point. A further discussion of potentiometry is found in Chapter The sample solution is titrated against a solution of silver nitrate of known concentration.

Mohr method of determination of chlorides by titration with silver nitrate is one of the oldest argentometdic methods still in use – it was researched and published by Karl Friedrich Mohr in To make result more realistic we can add small amount of chloride free calcium carbonate to the solution to imitate the white silver argentomeyric.


The blue line shows the complete titration curve. By using this site, you agree to the Terms of Use and Privacy Policy. From Wikipedia, the free encyclopedia.

Precipitation Titrations – Chemistry LibreTexts

It is also possible to use indirect argentometric methods for determination of anions, that create insoluble salts with silver I for example phosphate PO4, arsenate AsO4 and chromate CrO4. What are some example of the use of argentometric titration?

Because CrO 4 2— imparts a yellow color to the solution, which might obscure the end point, only a small amount of Argentometic 2 CrO 4 is added.

Both processes interfere with the determination accuracy. Sign up or log in Sign up using Google. Read number of moles and mass of chlorides in the titrated sample in the output frame.

Like, we use alkalimetric titration to calculate the real concentration of table vinegar. Retrieved from ” https: Post Your Answer Discard By clicking “Post Your Answer”, you acknowledge that you have read our updated tutration of serviceprivacy policy and cookie policyand that your continued use of the website is subject to these policies.